Consequences of Limescale
Some types of calcium and salts in water settle and accumulate in equipment
and pipes. Factors that accelerate the accumulation of scale are changes
in temperature, changes in pressure and whirlpools in the water.
Scale is not harmful to health but it destroys valuable equipment and causes
problems in pipes.
Scale problems are measured according to the degree of hardness in the
water (a product of the calcium and magnesium in the water).
Experts claim that
levels higher than 250 ppm are destructive to equipment and plumbing.
Crystallised scale in home plumbing accelerates corrosion, causes blockages,
leaks & serious expensive damage to pipes.
In industry, untreated scale can paralyse entire factories and sites.
Scale causes wasted electricity and gas because heating elements are ineffective.
Scale promotes the use of chemicals to remove accumulation on tiles and sinks,
and in kettles.
Scale causes repeated malfunctions of expensive household appliances like
washing machines and water heaters.


Limescale
http://en.wikipedia.org/wiki/Limescale
Limescale is the hard, off-white, chalky deposit found in kettles, hot-water boilers and the inside of inadequately maintained hot-water central heating systems. It is also often found as a similar deposit on the inner surface of old pipes and other surfaces where ‘hard water’ has evaporated.
These types of limescale differ slightly due to their origins. The type found deposited on the heating elements of water heaters etc. has a main component of calcium carbonate, precipitated out of the (hot) water. Hard water contains calcium (and often magnesium) bicarbonate and/or similar salts.
Calcium bicarbonate is soluble in water, however at temperatures above 70 °C the soluble bicarbonate is converted to poorly-soluble carbonate, leading to deposits in places where water is heated. Local boiling “hot spots” can also occur when water is heated, resulting in the concentration and deposition of salts from the water.
Calcium cations from hard water can also combine with soap, which would normally dissolve in soft water. This combination often forms scum which precipitates out in a thin film on the interior surfaces of baths, sinks, and drainage pipes. Soap usually contains salts of anions from neutralized fatty acids or similar chemical compounds. The calcium salts of these anions are less soluble in water.
The type found on air-dried cooking utensils, dripping taps and bathroom
tiling consists of calcium carbonate mixed with all the other salts that
had been dissolved in the water, prior to evaporation.
Corrosion has many serious economic, health, safety, technological,
and cultural consequences to our society.
Economic effects
Studies in a number of countries have attempted to determine the national
cost of corrosion. The most extensive of these studies was the one carried
out in the United States in 1976 which found that the overall annual cost
of metallic corrosion to the U.S. economy was $70 billion, or 4.2% of the
gross national product. To get a feeling for the seriousness of this loss,
we may compare it to another economic impact everyone is worried about – the
importation of foreign crude oil, which cost $45 billion in 1977.
Health effects
Recent years have seen an increasing use of metal prosthetic devices in
the body, such as pins, plates, hip joints, pacemakers, and other implants.
New alloys and better techniques of implantation have been developed, but
corrosion continues to create problems. Examples include failures through
broken connections in pacemakers, inflammation caused by corrosion products
in the tissue around implants, and fracture of weight-bearing prosthetic
devices. An example of the latter is the use of metallic hip joints, which
can alleviate some of the problems of arthritic hips. The situation has
improved in recent years, so that hip joints which were was at first limited
to persons over 60 are now being used in younger persons, because they
will last longer.
Safety effects
An even more significant problem is corrosion of structures, which can
result in severe injuries or even loss of life. Safety is compromised by
corrosion contributing to failures of bridges, aircraft, automobiles, gas
pipelines etc. – the whole complex of metal structures and devices
that make up the modern world.
Technological effects
The economic consequences of corrosion affect technology. A great deal
of the development of new technology is held back by corrosion problems
because materials are required to withstand, in many cases simultaneously,
higher temperatures, higher pressures, and more highly corrosive environments.
Corrosion problems that are less difficult to solve affect solar energy
systems, which require alloys to withstand hot circulating heat transfer
fluids for long periods of time, and geothermal systems, which require
materials to withstand highly concentrated solutions of corrosive salts
at high temperatures and pressures. Another example, the drilling for oil
in the sea and on land, involves overcoming such corrosion problems as
sulfide stress corrosion, microbiological corrosion, and the vast array
of difficulties involved in working in the highly corrosive marine environment.
In many of these instances, corrosion is a limiting factor preventing the
development of economically or even technologically workable systems.
Cultural effects
International concern was aroused by the disclosure of the serious deterioration
of the artistically and culturally significant gilded bronze statues in
Venice, Italy. Corrosive processes will accelerate the deterioration of
precious artifacts such as those in Venice by the highly polluted environments
that now are prevalent in most of the countries of the world. Likewise,
inside the world's museums conservators and restorers labor to protect
cultural treasures against the ravages of corrosion or to remove its traces
from artistically or culturally important artifacts.
Consequences of bacteria and algae
Bacteria
http://en.wikipedia.org/wiki/Bacteria
A bacterium (plural: bacteria) is a unicellular microorganism.
Typically a few micrometres in length, individual bacteria have a wide-range
of shapes, ranging from spheres to rods to spirals. Bacteria are ubiquitous
in every habitat on Earth, growing in soil, acidic hot springs, radioactive
waste, seawater, and deep in the Earth's crust. There are typically 40
million bacterial cells in a gram of soil and a million bacterial cells
in a millilitre of fresh water; in all, there are approximately five nonillion
(5×10
) bacteria in the world, forming much of the world's biomass.
Bacteria are vital in recycling nutrients, and many important steps in
nutrient cycles depend on bacteria, such as the fixation of nitrogen from
the atmosphere. However, most of these bacteria have not been characterised,
and only about half of the phyla of bacteria have species that can be cultured
in the laboratory. The study of bacteria is known as bacteriology, a branch
of microbiology.
There are approximately ten times as many bacterial cells as human cells
in the human body, with large numbers of bacteria on the skin and in the
digestive tract. Although the vast majority of these bacteria are rendered
harmless or beneficial by the protective effects of the immune system,
a few pathogenic bacteria cause infectious diseases, including cholera,
syphilis, anthrax, leprosy and bubonic plague. The most common fatal bacterial
diseases are respiratory infections, with tuberculosis alone killing about
2 million people a year, mostly in sub-Saharan Africa. In developed countries,
antibiotics are used to treat bacterial infections and in various agricultural
processes, so antibiotic resistance is becoming common. In industry, bacteria
are important in processes such as wastewate treatment, the production
of cheese and yoghurt, and the manufacture of antibiotics and other chemicals.
Bacteria are prokaryotes. Unlike cells of animals and other eukaryotes,
bacterial cells do not contain a nucleus and rarely harbour membrane-bound
organelles. Although the term bacteria traditionally included all prokaryotes,
the scientific classification changed after the discovery in the 1990s
that prokaryotic life consists of two very different groups of organisms
that evolved independently from an ancient common ancestor. These evolutionary
domains are called Bacteria and Archaea.
Algae
http://en.wikipedia.org/wiki/Algae
Algae are a large and diverse group of simple plant-like
organisms, ranging from unicellular to multicellular forms. The largest
and most complex marine forms are called seaweeds. They are considered
'plant-like' because
of their photosynthetic ability, and 'simple' because they lack
the distinct organs of higher plants such as leaves and vascular tissue.
Though the prokaryotic Cyanobacteria (commonly referred to as Blue-green
algae) were traditionally included as 'algae' in older textbooks,
many modern sources regard this as outdated and restrict the term algae
to eukaryotic organisms. All true algae therefore have a nucleus enclosed
within a membrane and chloroplasts bound in one or more membranes. Algae
constitute a paraphyletic and polyphyletic group: they do not represent
a single evolutionary direction or line, but a level or grade of organization
that may have developed several times in the early history of life on Earth.
Algae lack leaves, roots, and other organs that characterize higher plants.
They are distinguished from protozoa in that they are photosynthetic. Many
are photoautotrophic, although some groups contain members that are mixotrophic,
deriving energy both from photosynthesis and uptake of organic carbon either
by osmotrophy, myzotrophy, or phagotrophy. Some unicellular species rely
entirely on external energy sources and have reduced or lost their photosynthetic
apparatus.
All algae have photosynthetic machinery ultimately derived from the cyanobacteria,
and so produce oxygen as a byproduct of photosynthesis, unlike other photosynthetic
bacteria such as purple and green sulfur bacteria.
The consequences of Bacteria in applications where Hydropath Technology can be effective in combating the problem.
Bacteria causing diesis in cooling towers and swimming pools.
Bio fouling of heat exchangers power stations condenser and cooling towers and sea water heat exchangers. Increasing energy requirement.
Increase maintenance requirement due to blockage of filters.
Considerable increase of anti bio fouling chemicals causing damage to the environment.
Aluminium sulphate, written as Al2(SO4)3 or Al2O12S3, is a widely used
industrial chemical. It is sometimes incorrectly referred to as alum,
as it is closely related to this group of compounds. It occurs naturally
as the mineral alunogenite. It is frequently used as a flocculating agent
in the purification of drinking water and waste water treatment plants,
and also in paper manufacturing.
Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt.
It forms a number of different hydrates, of which the hexadecahydrate Al2(SO4)3•16H2O
and octadecahydrate Al2(SO4)3•18H2O are the most common.
It can also be very effective as a molluscicide, killing spanish slugs.
Recent research suggests aluminum sulfate may contribute to dementia and
Alzheimer's disease.
http://en.wikipedia.org/wiki/Aluminium_sulfate
Preparation
Aluminium sulphate may be made by dissolving aluminium hydroxide, Al(OH)3,
in sulfuric acid, H2SO4:
2Al(OH)3 + 3H2SO4 + 3H2O → Al2(SO4)3·6H2O
Uses
Aluminium Sulphate is used in water purification and as a mordant in dyeing
and printing textiles. In water purification, it causes impurities to coagulate
which are removed as the particulate settles to the bottom of the container
or more easily filtered. This process is called coagulation or flocculation.
When dissolved in a large amount of neutral or slightly-alkaline water,
aluminium sulphate produces a gelatinous precipitate of aluminium hydroxide,
Al(OH)3. In dyeing and printing cloth, the gelatinous precipitate helps
the dye adhere to the clothing fibres by rendering the pigment insoluble.
History
Due to its name, it has been linked to the legendary Camelot, and even
Camlann, but historians have been quick to refute these suggestions.
The town elected two members to the Unreformed House of Commons. It was
considered a rotten borough and its franchise was abolished in 1832.
In July 1988, the water supply to the town and the surrounding area was
contaminated when 20 tons of aluminium sulphate was poured into the wrong
tank at the nearby Lowermoor water works on Bodmin Moor near Bodmin. An
independent inquiry into the incident (the worst of its kind in British
history) was started in 2002, and a draft report issued in January 2005,
but questions still remain as to the long-term effects on the health of
local residents. Michael Meacher, who visited Camelford in his post as
environment minister, was said to have called the incident and its aftermath,
'A most unbelievable scandal.'

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